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Demonstration Experiment on Video

Colored Milk Shakes

Objective: Test for Water in Milk

Peter Keusch




German version




Supermarket product:
milk

Chemicals:
CuSO4 · 5 H20
CoCl2 · 6 H20
ethanol 99 %

Cobalt(II) chloride solution:  5 g CoCl2 · 6 H20 are dissolved in 60 ml ethanol 99 %.


Apparatus and glass wares:
hotplate
3 milk shake glasses
2 glass stirring rods
beaker 100 mL
petri dish d = 9 cm


Hazards and safety precautions:

Copper(II) sulfate is harmful when swallowed.
Cobalt(II) chloride is toxic. Risk of irreversible effects. May cause sensitization or allergic effects. May cause skin or eye irritation.
Ethanol is highly flammable.

Safety glasses and protective gloves required.


Experimental procedure:

Using a petri dish and a hot plate blue crystalline CuSO4 · 5 H20 is heated strongly until it turns white. Three milk shake glasses are filled with milk. Two spatula measures of the white copper sulfate are added to the milk in the first glass while stirring. The milk in the third glass is mixed with a saturated ethanolic solution of CoCl2 · 6 H2O.


Results:

The milk in the first glass turns greenblue, the milk in the third glass becomes pink.




Video clip
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Discussion and background:

When CuSO4 · 5 H20 is heated the water of crystallization is driven off and anhydrous cupric sulfate is formed. White CuSO4 turns blue again if water is present.

CoCl2 · 6 H20 is dissolved in ethanol to form a blue chloro complex. When water is added the chloro complex is converted to a pink hexaaqua complex.



Milk consists of 87 % water. Water serves
·   as a solvent for whey proteins, lactose, minerals and water-soluble vitamines (e.g. vitamine B2 = lactoflavin)
·   as a dispersing agent for fat and casein
·   as a medium for chemical reactions.
·   3 - 4 % is hydration water bound to protein and lactose crystals.


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