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Organic Chemistry Demonstration Experiments on Video
Chemistry Visualized

Peter Keusch, University of Regensburg




German version




"The intelligent use of audiovisual resources will depend upon how well we are able to integrate the technique of the filmmaker or the program producer with the technique and wisdom of the skillful teacher."

Jerome Bruner







DISCLAIMER OF LIABILITY: This website contains information about demonstration experiments which are potentially dangerous. This information is directed at qualified teachers. The author assumes no legal liability or responsibility for the use of the information contained on these pages. By accessing this site and any links from this page you understand and agree to release its author of any liability. If you do not wish to agree to this, please leave this page immediately!




Short Movies of Chemical Lecture Experiments


The videos on this site are taken without special lighting techniques. We have used a normal camcorder (Sony PD330E). Some filmed material was saved in the camera. In order to obtain best possible images, some produced videos were directly transfered to a computer using USB connector. The program Adobe Premiere Plus permits the cutting of videos, sharpening of images (enhancing brightness / contrast) and the insertion of text. Finally the AV files were converted into MPEG-1 format and Real Media files .rm.

Usually the download of a video file takes at least some minutes, because it must be downloaded in its entirety according to the traditional 'store-and-forward principle'. In streaming technology the user does not have to spend time downloading the complete video before viewing. The required wait is minimal. Only the beginning of the files is downloaded. A buffer of packets is formed. As soon as the buffer is full (usually just a matter of seconds), the file starts to play. This means the client player plays back the packets in a seamless stream. While the viewer is watching the video sequence and the information in the buffer is used up, the next portion of data is downloaded etc, until the entire file is played without any interruption. An example of this technique are Real Video (.rm) files served by a Real Video server. They are playable on Real Player.

The demonstrations available on this site

·   illustrate important aspects of chemistry (reaction types, dyes, synthetics, chemical technology, chemistry in every day life), involve substances or equipment that are not available in many schools, and/or are hazardous or cause problems of disposal.

·   The experiments are 'student and teacher friendly' - there is no overwhelming technology. In the experiment descriptions there is enough theoretical background to remind teachers and students of the theoretical context of the experiment.

·   Our project intends to accompany the experiment lectures of organic chemistry allowing thus to revive the life shown experiments as video versions. Students can use their time on the computer effectively. Students are free to review as often as they like. Videos containing experiments, can assist students in learning.

·   The videos allow the students to see experiments which they would not be able to perform themselves, for reasons of skill, safety, expensive apparatus and materials or limited resources such as fume cupboards.

To make the video presentation (via intenet / local net) visible to students in a classroom or lecture hall a beamer (multimedia projector) and a projection screen will be needed.

In order to prevent possible misunderstandings it seems necessary to underline: The most important medium used in chemical education is not the computer, is not the beamer, is not the overhead projector, is not the video - the most important medium is the life shown experiment, which is performed on an open chemical demonstration bench.

'The real understanding arises only through practical experience'.


Under certain circumstances it proves to be useful to present an experiment on video.

·   In the case of experiments, which take a long time to complete, the movies can be composed of some single short video sequences allowing to show the essential experimental steps.

·   The videos show details (gas evolution on the surface of electrodes, interface between immiscible liquids, formation of 'Schlieren' etc.) that would be missed by students sitting far from the demonstration bench.


Reference:
Experimente auf Video

















Special Thanks

Patricia Fuchs, Markus Fischl, Rajka Frank, Martin Candussio, Mario Rodler, Tobias Hein,
Daniela Helfensdörfer and Ingo Stephan
have contributed substantially to the development of this presentation.
I'd just like to recognize and thank them for their assistance.





Addition Reactions:

Reaction of Cyclohexene with Bromine and Permanganate
Objective: Test for the C - C Double Bond
Experiment Description Video
02:48 min
Addition of Bisulfite to Aldehydes
Objective: Nucleophilic Addition to Carbonyl
Experiment Description Video
03:09 min
Addition of 2,4-Dinitrophenyl hydrazine to Aldehydes and Ketones
Objectives: Nucleophilic Addition to the Carbonyl Function, Addition-Elimination
Experiment Description Video
02:27 min

Substitution Reactions:

Reaction of Butylbromide Isomers with Silver Nitrate
Objective: Nucleophilic Substitution
Experiment Description Video
03:00 min
Hydrolysis of Butyl Bromide Isomers
Objective: Nucleophilic Substitution
Experiment Description Video
02:18 min
Hydrolysis of tertiary Butylhalides
Objectives: Nucleophilic Substitution, Effect of the Leaving Group on Rate
Experiment Description Video
00:55 min
Iodoform Reaction - Test for thea-Methyl Carbonyl Group
Objectives: Nucleophilic Carbonyl a-Substitution
Experiment Description Video
02:40 min
Azo Coupling
Objective: Electrophilic Aromatic Substitution, Acidic Azo Dyes
Experiment Description Video
01:15 min

Redox Reactions:

Reaction of Dihydroxybenzene Isomers with Ferric Chloride
Objective: Distinction between Catechol, Resorcinol and Hydroquinone
Experiment Description Video
01:09 min
Oxidation of the Butanol Isomers
Objective: Distinction between primary, secondary and tertiary Alcohol
Experiment Description Video
01:15 min
Redox System Benzoquinone / Hydroquinone (1)
Objective: Reduction of p-Benzoquinone with Iodide
Experiment Description Video
02:06 min
Redox System Benzoquinone / Hydroquinone (2)
Objective: Reduction of p-Benzoquinone by Disulfite via the Charge-Transfer-Complex Quinhydrone
Experiment Description^ Video
02:33 min

Test Reactions:

Fehling's Test
Objectives: Test for Reducing Sugars, Keto-Enol-Tautomerism, Copper-Tartrate-Complex
Experiment Description Video
05:08 min
Tollens Reaction - Silver Mirror Test
Objective: Test for Aldehydes
Experiment Description Video
03:30 min
Schiff's Reagent
Objective: Test for Aldehydes
Experiment Description Video
02:59 min
Biuret Reaction - Protein in Egg Albumen
Objectives: Test for Peptides and Proteins
Experiment Description Video
02:14 min
Xanthoproteic Test
Objective: Test for Aromatic Rings in Proteins
Experiment Description Video
02:00 min

Keto-Enol-Tautomerism:

Keto-Enol-Tautomerism of Ethyl Acetoacetate
Objective: Test for Enol Form, Fe(III) Complex
Experiment Description Video
05:25 min

Carboxylic Acids and Derivates:

Reaction of Carboxylic Acids with Magnesium
Objective: Relationship between Reactivity and Acid Strength
Experiment Description Video
02:25 min
Acid catalyzed Esterification - Test for Water (formed in this Reaction)
Objectives: Catalysis, Equilibrium, Le Chatelier's Prinziple
Experiment Description Video
01:23 min
Cis/trans Isomerization of Maleic Acid
Objectives: Light-induced Reaction, Isomerization
Experiment Description Video
03:21 min

Radicals and Radical Ions:

Reduction of Viologen Dication. Experiment Description Video
2:08 min
Oxidation of 1,3,5-Triphenylverdazyl Experiment Description Video
01:40 min
Wurster's Blue Experiment Description Video
02:00 min
Reaction of Benzil with Benzoin Experiment Description Video
01:43 min

Catalytic Reactions:

Decomposition of Hydrogen Peroxide with Catalase
Objectives: Enzyme Catalysis, Denaturation of Enzymes by Heavy Metal Salts
Experiment Description Video
01:23 min
Decomposition of Urea with Urease
Objectives: Enzyme Catalysis, Substrate Specifity, Competitive Inhibition
Experiment Description Video
02:33 min
Phase Transfer Catalysis (PTC) - Host-Guest Chemistry
Objectives: Extraction of Methylene Blue and Potassium Permanganate from the Aqueous Phases, Complexation with Sodium dodecylsulfate and Crown Ether, Host-Guest Complexes
Experiment Description Video 1
03.00 min

Video 2

03.00 min

Kinetics:

Landolt Reaction - Iodine Clock Kinetics
Objective: Effect of Concentration on the Rate of a Reaction
Experiment Description Video
02:00 min
Briggs-Rauscher Reaction
Objective: Mechanism of an Oscillating Reaction
Experiment Description Video
01:55 min
Belousov-Zhabotinsky-Reaction
Objective: Mechanism of an Oscillating Reaction
Experiment Description Video
03:26 min

Dyes:

Dyeing with Substantive Dyes
Objectives: Direct Dyeing, Phthalocyanines, Light and Washing Fastness
Experiment Description Video
03.00 min
Dyeing with Vat Dyes
Objectives: Indanthren Yellow G, Light and Washing Fastness
Experiment Description Video
04.50 min
Crystal Violet - a pH Indicator
Objective: Protonation of Crystal Violet
Experiment Description Video
02.00 min
Azo Dye Formation
Objectives: Diazotation, Coupling
Experiment Description Video
01.28 min
Positive Solvatochromism
Objectives: Shift of the Spectrum, Solvent Polarity
Experiment Description Video
02:14 min
Negative Solvatochromism
Objectives: Shift of the Spectrum, Solvent Polarity
Experiment Description Video
06:50 min
Chemiluminescence - The Glowing Spiral
Objective: Chemiluminescence
Experiment Description Video 1
01:13 min

Video 2
01:26min

Chromatographical Separation Methods:

Separation of Food Dyes by Thin Layer Chromatography (TLC)
Objectives: Chromatographic Method, Food Dyes
Experiment Description Video
02.50 Min
Separation of Lipohilic Dyes by Thin Layer Chromatography (TLC)
Objectives: Chromatographic Method, Lipophilic Dyes
Experiment Description Video
02.35 Min
Separation of Plant Pigments by Thin Layer Chromatography (TLC)
Objectives: Chromatographic Method, Plant Pigments
Experiment Description Video
03:13 min
Separation of Plant Pigments by Column Chromatography (CC)
Objectives: Chromatographic Method, Plant Pigments
Experiment Description Video
07:24 min

Synthetics:

Preparation of a Phenoplast Resin
Objectives: Polycondensation, Thermosetting Plastic
Experiment Description Video
04:22 min/td>
Preparation of Polyurethane Foam
Objective: Polyaddition
Experiment Description Video
03:40 min
Synthesis of Nylon 6,10
Objective: Interfacial Polycondensation
Experiment Description Video
04:45 min
Synthesis of Nylon 6 (Perlon)
Objective: Polymerization
Experiment Description Video
03:35 min

Chemical Technology:

Foam Plastic Styropor® - Polystyrene Processing
Objective: Pre-foaming, Drying, Mold foaming
Experiment Description Video
06:47 min
Catalytic Cracking Process
Objective: Catalytic Splitting of Hydrocarbons
Experiment Description Video
04:37 min

Chemistry in Every Day Life - Household and Supermarket Products:

The Tragedy of a Nice Beer Foam Head
Experiment Description Video
01.55 min
Colored Milk Shakes
Objective: Test for Water in Milk
Experiment Description Video
02.10 min
True Salmon or Salmon Substitute?
Objective: Test for Food Dyes
Experiment Description Video
03.10 min
Cabbage - red or blue?
Objective: Anthocyanins as pH Indicators
Experiment Description Video
03:20 min
Reaction of Leavening Ingredients with the Dye of Hybiscus Tea
Objective: Malvin a pH Indicator
Experiment Description Video
02:50 min
Black Tea - an "Iron Robber"
Objective: Polyphenol-Iron Complex
Experiment Description Video
02:06 min
Starch - widely available in many Foods
Objective: Starch-Iodine Complex, Test for Starch in Noodles and Rice
Experiment Description Video
00:48 min
Starch Products: Cream Stabilizer and Tart Glaze
Objective: Test for Starch
Experiment Description Video
02:05 min
Test for Amylase in Bee Honey
Objective: Enzymatic Hydrolysis of Starch
Experiment Description Video
03.20 min
Hartshorn Salt - Leavening Ingredient in Baking Powder
Objectives: Decomposition of Ammonia Bicarbonate, Test for Ammonia
Experiment Description Video
02:15 min
Carbonization of Emser Salt - Formation of a Black "Pharao-Snake"
Objectives: Test for Sugar and Sodium Bicarbonate
Experiment Description Video
03.20 min
Vegetarian and conventional Gummy Bears
Objective: Swelling Capability of the Biopolymer Gelatin
Experiment Description Video
01.05 min
Chlorophyllin keeps Canned Vegetable looking fresh
Objectives: Chlorophyllin-Copper-Complex, Food Dye
Experiment Description Video
01.35 min
Artificial Honey - a Sweet Imitation
Objective: Hydrolytic Decomposition of Sucrose, Invert Sugar
Experiment Description Video
02.35 min
Yeast and Sugar - The Chemistry must be right
Objective: Alcoholic Fermentation
Experiment Description Video
02.30 min
Unsaturated Fatty Acids - Important Components of Plant Oils
Objetive: Test for the Unsaturated Character
Experiment Description Video
03.55 min
Bromine destroys Carotene in Ketchup
Objective: Electrophilic Addition to the C - C Double Bond
Experiment Description Video
02:27 min
Bullrich Salt against an Excess of Gastric Acid
Objectives: Neutralization, Bicarbonate as an Antacid
Experiment Description Video
02.00 min
Chlorine Cleaner - not completely harmless
Objective: Bleaching Effect of Chlorine
Experiment Description Video
03.00 min
Amylase makes Detergents more effective
Objective: Test for Amylase
Experiment Description Video
02.20 min
Cellulases - Additives to Detergents
Objectives: Test for Cellulase, Bleaching Agents, Optical Brighteners
Experiment Description Video
01.45 min
Anionic Tensides in Powdered Laundry Detergents
Objective: Surface-active Agents
Experiment Description Video
03.15 min
Emulgators - "Mediators" between Water and Oil
Objectives: Amphiphilic Nature of Emulgators, Interfacial Tension
Experiment Description Video
02.25 min
Vitamin C - a Potent Antioxidant
Objective: Reducing Ability of Ascorbic acid
Experiment Description Video
01.30 Min
How to peel an uncooked egg
Objective: Release of Carbon dioxide from Calcium carbonate
Experiment Description Video
01.25 Min
Hard Water kills Soap
Objective: The Influence of Hard Water on the Washing Process
Experiment Description Video
01.00 min
White Wine, made from Red Wine
Objective: Charcoal an Adsorption Agent
Experiment Description Video
02.00 min
White Sugar - Black Carbon
Objectives: Decomposition of Organic Matter, Dehydrating Effect of Concentrated Sulfuric Acid
Experiment Description Video
02.30 min
Flash Point of ignitable Liquids
Objectives: Flash Point, Flame Point
Experiment Description Video
01.00 Min

"Magical" Chemistry:

'One Cola and one Beer, please' - Modified Landolt Reaction
Objective: Reaction Rate

Experiment Description Video
01:12 min
Cocktail 'Old Nassau' - Modified Landolt Reaction
Objective: Reaction Rate
Experiment Description Video
00:52 min
Chemical Traffic Lights
Objectives: Solubility, Polarity, Salting-Out Effect
Experiment Description Video
05:42 min
A Strawberry Sundae - not even delicious-looking
Objective: Enzymatic Decomposition of Hydrogen Peroxide
Experiment Description Video
00:35 min
It is not always gold that glitters!
Objective: "Silver and gold plating" of copper coins
Experiment Description Video
00:35 min